Circular No. 15/99 - Recommendations for the Carriage of Calcium Hypochlorite
NOVEMBER 30, 1999
CIRCULAR NO. 15/99
TO MEMBERS OF THE ASSOCIATION
RECOMMENDATIONS FOR THE CARRIAGE OF
CALCIUM HYPOCHLORITE: UN NOS. 1479, 1748, 2208, 2880
Over the past two years there have been several large fires in cargo ships attributable to the carriage of calcium hypochlorite. In response to these casualties the International Group of P&I Clubs established a calcium hypochlorite working group which has met to share information and listen to the views of scientific experts.
The results of full-scale tests on package sizes routinely used when shipping calcium hypochlorite in freight containers indicates that the transport requirements in the IMDG Code are inadequate.
Calcium hypochlorite is classed as an oxidizing substance (IMDG Class 5.1). It is manufactured in various forms, both high strength ("HCH") and low strength known as bleaching powder. This accounts for the various UN classifications. All forms of calcium hypochlorite will react violently when contaminated by an organic material. The reaction will generate heat and oxygen, which will feed any resulting fire. Impurities can be introduced either via insufficient or damaged packing material, or alternatively due to poor manufacturing standards. The product is also self-reactive and sensitive to high temperatures: sensitivity increases as the package size increases.
Recent research on hydrated HCH (UN 2880) indicates that a violent reaction can occur at temperatures encountered by vessels transiting tropical areas. The critical ambient temperature (the temperature at which a violent decomposition of the material occurs) for a 20ft freight container packed with 432 drums of 40 kg (net) of UN 2880 is calculated by the scientists to be about 37° C. The critical ambient temperature for a 20ft freight container packed with 80 drums of UN 2880 of 200 kg (net) is calculated to be about 30° C. For a violent reaction to occur, these temperatures would have to be maintained for up to 3 weeks, although at higher temperatures (or if the product is impure) this period is reduced considerably.
The IMDG code today allows UN 2880 to be shipped below deck but "Away from sources of heat where temperatures in excess of 55° C for a period of 24 hours or more will be encountered."
In light of the results of the investigation into the thermal properties of hydrated HCH (UN 2880), the International Group believes that this provision is inadequate and has requested IMO to review all entries in the IMDG Code concerning the requirements for transportation of all forms of calcium hypochlorite.
Realizing the product’s importance in providing clean water to disaster-struck areas, and taking into account an envisioned delay before any changes to the IMDG Code will take effect, the International Group of P&I Clubs has decided to issue interim recommendations for the carriage of calcium hypochlorite cargoes. The purpose of these guidelines is to enable the continued shipping of calcium hypochlorite in a way that will reduce the risk of exposing the carrying vessel and shipboard personnel to danger, until such time as the IMDG Code has been reviewed by IMO.
Accordingly, the Group’s recommendations are as follows:
Joseph E.M. Hughes, Chairman & CEO
Shipowners Claims Bureau, Inc., Managers for
THE AMERICAN CLUB